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To get the correct hour of the day, you will first need to find out what time the sun rises in your location. You can find out the sunrise/moon rise time worldwide by going here: Sunrise hours

Example:  If you live in DC and want to do a love spell, you should choose Friday during the hour of Venus. I choose February 16th. Since the sun rises in DC at 0725, and the first hour of the day on Friday is attributed to Venus, the ritual should commence at 0725 in the day, or at 12:11 at night, since the sun sets at 5:11.